RE: CO2 and Reefs
CO2 will decrease the alkalinity because the carbonate is used up in neutralizing the carbon acid that the CO2 is converted into.
I thin NaCl_H2O ran into this in his home. He found a partial solution by venting his monster skimmer into the attic where the air didn't have as much CO2. So, there are some anlogies to the aquarium hobbyist. The CO2 that you generate through respiration, from your pets, from cooking and heating, and from smoking are similar to what we are seeing in the global warming models being discussed in this article.
Gary
125 SPS, 75 gal. LPS/softie reef, 9 gal. Nano